The kinematic apse and jz‐preserving propensities for nonreactive, dissociative, and reactive polyatomic collisions

We consider the generalization of the kinematic apse to nonreactive polyatom–polyatom impulsive collisions, dissociative atom–molecule impulsive collisions,and (partially) impulsive reactive atom–diatom collisions. Appropriate generalizations of the kinematic apse are obtained along which there is a classical propensity for preserving the projection of the total intrinsic spin. In the case of reactive scattering, we discuss several different situations for which such a propensity occurs. For reactive systems in which no such propensity exists, the analysis may still provide a basis for classifying reactions. Disciplines Biological and Chemical Physics | Physics Comments This article is published as Hoffman, D. K., J. W. Evans, and D. J. Kouri. "The kinematic apse and jz‐preserving propensities for nonreactive, dissociative, and reactive polyatomic collisions." The Journal of chemical physics 80, no. 1 (1984): 144-148, doi:10.1063/1.446498. Posted with permission. This article is available at Iowa State University Digital Repository: http://lib.dr.iastate.edu/physastro_pubs/438 The kinematic apse and iz·preserving propensities for nonreactive, dissociative, and reactive polyatomic collisions D. K. Hoffman and J. W. Evans Ames Laboratory. USDOE, aJ and Department of Chemistry, Iowa State University, Ames, Iowa 50011